Kenneth Kang
Wednesday, June 25, 1997
Term Definition Valence the electrons in the highest occupied energy level of an ElectronsValence element's atom Electrons isoelectronicisoelec two ions that share an electron shell configuration tronic Electron dot a depiction of valence electrons as dots drawn around the structuresElectron symbol of the element dot structures octet ruleoctet Atoms react by changing the number of their electrons so rule as to acquire the stable electron structure of a noble gas. anionanion negatively charged ion cationcation positively charged ion halied ionshalied the Ions that form from group 7A ions ionic bondbondionic forces of attraction that bind opposite charged ions together coordination the number of ions of opposite charge that surround each numbercoordination ion in a crystal number metallic consist of the attraction of the free-floating valence bondbondmetallic electrons for the positively charged metal ions
Table 1: Chapter 13 Terms
Term Definition structure chemical formulas that show the arrangement of atoms in formulastructure molecules and polyatomic ions formula single covalent formed when a pair of electrons is shared between two bondbondsingle atoms covalent unshared pairsunshared the pairs of valence electrons that are not shared pairs between atoms double covalent two shared pairs of electrons bondbonddouble covalent triple covalent three shared pairs of electrons bondbondtriple covalent coordinate covalent when one atom contributes both bonding electrons in a bondbondcoordinate covalent bond covalent resonanceresonance when two or more equally valid electron dot structures can be written for a molecule paramagneticparamagneti a substance that shows a relatively strong attraction c to an external magnetic field molecular the overlapping atomic orbitals of two covalently orbitalmolecular bonded atoms orbital bonding orbitalbonding a molecular orbital whose energy is lower than that of orbital the atomic orbitals from which it is formed antibonding a molecular orbital whose energy is higher than that of orbitalantibonding the atomic orbitals from which it is formed orbital sigma bondbondsigma a bonded orbital that is symmetriacal along the axis connecting the two nuclei pi bondbondpi a sausage-shaped region above and below the bond axis tetrahedral 109.5° angletetrahedral angle VSEPR theoryVSEPR because electrons paires repel, molecules adjust so theory that the valence-electron are as far apart as possible (valence-shell electron-pair repulsion) hybridizationhybridizat several atomic orbitals mix to form the same number of ion equivalent hybrid orbitals nonpolar covalent a bond where electrons are shared equall y bondbondnonpolar covalent polar covalent a bond of two unlike atoms where electrons are hogged bondbondpolar covalent by one of them polar bondbondpolar the same as a polar covalent bond polar moleculepolar one end is slightly negative and the other end is molecule slightly positive dipoledipole a molecule with two poles bond dissociation the energy required to break a single bond energybonddissociation energy van der Waals all weak attractions between molecules forcesvan der Waals forces dispersion weakest of all molecular interactions-thought to be forcesdispersion caused by the motion of electrons forces dipole polar molecules' attraction to one another interactionsdipole interactions hydrogen attractive forces in which hydrogen that is covealently bondbondhydrogen bonded to a very electronegative atom in the same molecule or a nearby molecule network solidsnetwork stable substances whose atoms are all covalently bonded solids to each other
Table 2: Chapter 14 Terms
Terms Definition surface the inward force or pull which tends to minimize the surface tensionsurface area of a liquid tension surfactantssurfac decreases surface tension (SURFace ACtive AgeNTS) tants aqueous water samples containing dissolved solids solutionsaqueous solutions solventsolvent the dissolving medium solutesolute the dissolved particles solvationsolvatio a solute dissolving n effloresceefflore when a hydrate, with a higher vapor pressure than water, sce loses the water of hydration water of water in a crystal hydrationwater of hydration hygroscopichygros compounds that remove moisture from air copic desiccantsdesicca hydgroscopic substances that are used as drying agents nts deliquescentdeliq compounds that remove sufficiant water from the air to uescent dissolve and form solutions electrolyteselect compounds that conduct an ellectric current in aqueous rolytes solution or molten state nonelectrolytesno coumpouds that do not conduct an electric current in aqueous nelectrolytes solution or the molten state weak a solution where only a fraction of the solute exists as ions electrolyteelectr olyteweak strong a large portion of the solute exists as ions when dissolved electrolyteelectr olytestrong suspensionssuspen mixtures from which some of the particles will settle slowly sions upon standing colloidscolloids mixtures containing particles that are intermediate in size between those of suspensions and true solutions Tyndall the scattering of visible light in all directions effectTyndall effect Brownian the chaotic movement of collodial particles motionBrownian motion emulsionsemulsion colloidal dispersion of liquids in liquids s
Table 3: Chapter Terms
Terms Definition saturated a solution conting the maximum amount of solute for a solutionsaturated given amount of solvent at a constant temperature solution solubilitysolubility the amount of substance that dissolves in a given quantity of solvent at a given temperature to produce a saturated solution unsaturatedunsaturated a solution that contains less solute than a saturated solution misciblemiscible two liquids that dissolve each other immiscibleimmiscible liquids that are insoluble in one another Henry's LawHenry's at a given temperature, the solutbility of a gas in a Law liquidis directly proportional to the pressure of the gas above the liquid supersaturated a solution which containes more solute than it can solutionsupersaturated theoretically hold at a given temperature solution concentrationconcentra a measure of the amount of solute that is dissolved in a tion given quantity of solvent dilute solutiondilute a solution that contains only a small amount of solute solution concentrated a solution that contains a large amount of solute solutionconcentrated solution molaritymolarity the number of moles of a solute dissolved in 1 L of solution colligative properties that depend on the number of dissolved propertiescolligative particles of a given mass of solvent properties boiling point the difference in temperature between the boiling points elevationboiling of a solution and of the pure solvent point elevation freezing point the difference in temperature between the freezing depressionfreezing points of a solution and of the pure solvent point depression molalitymolality the numnber of moles of solute dissolved in 1 kilgram of solvent mole fractionmole the ratio of the moles of solute in solution to the fraction total number of moles of both solvent and solute molal boiling point (Kb of Tb = Kbm ) the change in boiling point for a 1 elevation molal solution of a nonvolatile molecular solute constantmolal boiling point elevation constant molal freezing point the change in the freezing point for a 1 molal solution depression of a nonvolatile molecular solute constantmolal freezing point depression constant
Table 4: Chapter 16 Terms
Chapter 25 Hydrocarbon Compounds
Terms Definition alkanesalkanes hydrocarbons that contain only single covalent bonds continuous chain contain any number of carbon atoms in a straight alkanescontinuous chain chain alkanes homologous constant increament of change in molecular structure serieshomologous series from one compound in the series to the next condensed structural diagrams which leave out some bonds and atoms from formulacondensed the structural formula structural formula IUPAC SystemIUPAC System the system of naming organic compounds (International Union of Pure and Applied Chemistry) substituentsubstituent an atom or a group of atoms that can take the place of a hydrogen atom on a parent hydrocarbon molecule alkyl groupalkyl group a hydrocarbon substituent branced chain an alkane with one or more alkyl groups alkanebranced chain alkane hydrocarbonshydrocarbons organic compounds that contain only carbon and hydrogen structural compounds that have the same molecular formula but isomersstructural isomers different molecular structures unsaturated organic compound containing double and triple compoundsunsaturated carbon-carbon bonds compounds alkenesalkenes organic compounds containing carbon-carbon double bonds alkynesalkynes organic compounds containing carbon-carbon triple bonds trans configurationtrans where the substituted groups are o opposite side s configuration of the double bond cis configurationcis where the substitued groups are on the smae side of configuration the double bond geometric where compounds differ only in the geometry of their isomersgeometric isomers substituted groups asymmetric a carbon with four different groups attached carbonasymmetric carbon stereoisomersstereoisomers molecules of the same molecular structure that differ only in the arrangement of the atoms in space cyclic hydrocarbonscyclic caompounds that contain a hydrocarbon ring hydrocarbons aliphatic all hydrocarbons compounds which do not contain compoundsaliphatic rings compounds arenesarenes unsaturated cyclic hydrocarbons aromatic compoundaromatic any substance in whic the bonding is like that of compound benzene crackingcracking a controlled process by which hydrocarbons are broken down or rearranged into smaller, more useful molecules
Table 5: Terms
Term Definition functional a specific arrangement of atoms in an organic compound that is groupfunctional capable of characteristic chemical reaction group halocarbonshaloc a class of organic compounds containing covalently bonded arbons fluorine, chlorine, bromine, or iodine alkyl halocarbons in which a halogen is attached to a carbon of an halidesalkyl aliphatic chain halides aryl halocarbons in which a halogen is attached to a carbon of an halidesaryl arene ring halides substitutionsubs the replacement of an atom or group of atoms by another atom titution or group of atoms alcoholalcohol organic compounds with ah -OH group hydroxyl the -OH group in alcohols grouphydroxyl group fermentationferm the production of ethanol from sugars by the action of yeast entation or bacteria denatured ethanol with an added substance to make it toxic alcoholdenatured alcohol addition a substance is added at the double or triple bond of an alkene reactionaddition or alkyne reaction hydration the addition of water to an alkene reactionhydratio n reaction hydrogenation hydrogen is added to a carbon-carbon double bond to give an reactionhydrogen alkane ation reaction carbonyl carbon atom and an oxygen atom joined by a double bond groupcarbonyl group aldehydesaldehyd organic compounds in which the carbonyl group is always joined es to at lease one hydrogen: RCHO ketonesketones organic compounds in which the carbon of the carbonyl group is joined to two other carbons: RCOR carboxylic compounds with a carboxyl group actidscarboxylic actids carboxyl a carbonyl group attached to a hydroxyl group groupcarboxyl group fatty contiuous chain carboxylic acids acidsfatty acids esthersesthers compounds in which oxygen is bonded to two carbon groups: R-O-R dehydrogenation the loss of hydrogen reactiondehydrog enation reaction Benedict's used for aldehyde detection testBenedict's test & Fehling's testFehling's test estersesters derivatives of carboxylic acids in which the -OH of the carboxyl group has been replaced by an -OR from an alcohol polymerpolymer a large molecule formed by the covalent bonding of repeating smaller molecules monomersmonomers molecules tha t combine top form the repeating unit of a polymer carbohydratecarb monomers and polymers of aldehydes and ketones that have ohydrate numerous hydroxy groups attached monosaccharidesm simplest carbohydrate molecules, simple sugars onosaccharides disaccharidesdis sugars which are formed from two monosaccharides accharides polysaccharidesp the linkage of many monosaccharide monomers olysaccharides lipidlipid a larg class of relatively water-insoluble compound that includes fats, oils, and waxes waxeswaxes esters of long-chain fatty acides and long-chain alcohols triglyceridestri triesters of long chain fatty acids and glycerol glycerides saponificationsa hydrolysis of oils or fats by boiling them with aqueous sodium ponification hydroxide, making soap amino acidamino a compound whch contains amino (-NH4) and carboxylic acid acid (-COOS) groups in the same molecule zwitterionszwitt internal salts of amino acids erions peptidepeptide any combination of amino acids in which the amino group of one acid is united with the carboxylic acid group of another peptide the bond between the carbonyl rgoup of one amino acid and the bondpeptide nitrogen of the next amino acid in the peptide chain bond polypeptidepolyp any peptide with more than ten amino acid residues eptide proteinprotein a peptide with more than about 100 amino acids nucleic acids polymers found primarily in cell nuclei nucleotides monomers that make up DNA and RNA
Table 6: Terms
Term Definition reaction ratereaction the number of atoms, ions or molecules that react in a rate give time to form products activation the minumum energy colliding particles must have in energyactivation order to react energy activated the arrangement of atoms at the peak of the activation complexactivated energy barrier complex transition the activated complex statetransition state heterogeneous reactions carred out with heterogeneous miztures of reactionsheterogeneous reactants reactions inhibitorinhibitor a substance that interferes with catalysis rate lawrate law e.g. specific rate a proportinality constant relating the concetration of constantspecific rate reactants to the rate of reaction constant first-order the reaction rate is proporional to the concentration of reactionfirst-order only one reactant reaction elementary reactants are concerted to products in a single step reactionelementary reaction reaction all of the elementarty reactions of a complex reaction mechanismreaction mechanism intermediateintermedia a product of areaction that immediate becomes a reactant te of another reaction law of disorderlaw of things move spontaneously in the direction of maximum disorder chaos or disorder entropyentropy the measure of disorder of a system standard of the substance at a stable state at 25 °C and 1 atm entropystandard of entropy spontaneous reactions that are known to produce the written products reactionspontaneous reaction non-spontaneous do not give products under the specified conditions reactionsnon-spontaneo us reactions free energyfree the energy availible to do work when a reaction occurs energy exergonicexergonic spontaneous reactions that release free energy endergonicendergonic nonspontaneous reactions that absorb free energy Gibbs free energy, is the maximum amount of energy that can be coupled to change inGibbs free another process to do useful work energy, change in reversible the conversion of reactants into products and the reactionreversible conversion of products into reactants occur reaction simultaneously chemical when the forward and backward reactions are taking place equilibriumchemical at the same rate equilibrium equilibrium the relative concentration of the reactants and products positionequilibrium at equilibrium position equilibrium Keq, the ratio of product concentrations to reactant constantequilibrium concentrations with each concentration raied to the constant power given by the number of moles of that substance in the balanced chemical equation Châtelier's If a stress is applied to a system in a dynamic principleChâtelier's equilibrium, the system changes to relive the stress principle
Table 7: Chapter 17
The kinetic theory of reaction / matter is where the particles have to collide with enough energy against each other. Reaction rates are affected by temperature, concentration, particle size, and catalysts.
Term Definition hydroxide ionhydroxide ion OH- hydronium ionhydronium ion H3O+ self-ionizationself-ionizat the reaction in which two water molecules react to ion give ions neutral solutionneutral any aqueous solutio in which the H+ and the OH- solution concentrations are 1.0 10-7 mol / L ion-product constant for the product of concetrations of the hydrogen ions waterion-product constant and hydroxide ions in water for water acidic solutionsacidic the H+ concentration is greater than the OH- solutions concentration basic solutionsbasic the H+ concentration is less than the OH- solutions concentration alkaline solutionsalkaline same as basic solutions solutions *pH the negative logarithm of the hydrogen-ion concentration monoprotic acid any acid that containese one ionizable hydrogen diprotic acid any acid that contains two ionizable protons triprotic acid any acid that containes three ionizable protons hydrogen-ion donor the Brønstead-Lowry theory's acid hydrogen-ion acceptor the Brønstead-Lowry theory's base conjugate acid the particle formed when a base gains a hydrogen ion conjugate base the particle formed when an acid has donated a hydrogen ion conjugate acid-base pair two substances that are related by the loss or gain of a single hydrogen ion amphoteric a substance that can act as both an acid and a base Lewis acid a substance that can accept a pair of electrons to form a covalent bond Lewis base a substance that can donate a pair of electrons to form a covalent bond weak acids acids that ionize only slightly in aqueous solution acid dissociation constant the ratio of the concentration of the dissociated form of an acid to the undissociated form strong bases bases that dissociate completely into metal ions and hydroxide ions in aqueous solution strong acids acids that completely ionize in aqueous solution weak bases bases that do not dissociate completely in aqueous solution base dissociation constant the ratio of the concentration of the dissociated form of a base to the undissociated form
Table 8: Chapter 18
Terms Definition neutralization reactions bin which an acid and a base react in an aqueous reaction solution to produce a slat and water standard solution the solution of known concentration end point the point at which neutralization is acheived titration the addition of a known amount of solutoin to determine the volume or concentration of another solution equivalentequivalent the amount of an acid or base that will give one mole of hydrogen or hydroxide ions gram equivalentgram the mass of one equivalent of a substance equivalent normalitynormality the concentration expressed as the number of equivalents of solute in 1 L of solution equivalence the point of neutralization pointequivalence point salt hydrolysissalt the cation or anions of the dissociated salt accept hydrolysis hydrogen ions from water or donate hydrogen ions to water buffersbuffers solutions in which the pH remains relatively constant when small amounts of acid or base are added buffer the amount of acid or base that may be added to a buffer capacitybuffer solution before a significant change in pH occurs capacity solutbility product the product of the concentration terms each raised to the constantsolutbility power of the coefficient of the substance in the product constant dissociation equation common ioncommon an ion that is common to both salts ion common ion the lowering of the solubility of a substance by the effectcommon ion addition of a common ion effect
Table 9: Chapter 19
Term Definition oxidation--reduction the chemical changes that occur when electrons are reactionsoxidation--reducti transferred between reactants on reactions redox reactionsredox oxidation--reduction reactions reactions oxidationoxidation -the combination of an element with oxygen -loss of electrons reductionreduction -the loss of oxygen from a compound -gain of electrons reducing agentreducing the substance in a redox reaction that donates agent electrons oxidizing agentoxidizing the substance in a redox reaction that accepts agent electrons oxidation numberoxidation a positive or negative number assiggned to an atom number according to a set of arbitrary rules oxidation number change a redox equation is balanced by comparing the methodoxidation number increases and decreases in oxidation number change method half-reaction the method used to balance redox equations by methodhalf-reaction method balancing oxidation and reduction half-reactions half-reactionhalf-reaction an equation showing either the reduction or the oxidation of a species in an oxidation-reduction reaction
Table 10: Chapter 20
Terms Definition radioactivityradioac the process by which uranium gives off rays tivity radiationradiation the penetrating rays emmited by a radioactive substance radioisotopesradiois certain isotopes that have unstable nuclei otopes radioactive the process by which an unstable nucleus loses energy by decayradioactive emitting radiation decay alpha helium nuclei radiationalpha radiation alpha two protons and two neutraons which have a double postive particlesalpha charge. particles beta raditationbeta fast moving electrons raditation gamma electromagnetic radiation radiationgamma radiation band of neutron v proton plot stablityband of stablity positronpositron a particle with the mass of an electron but a postive charge half-lifehalf-life the time required for one-half of the atoms of a radioisotope to emit radition and decay to products transmutationtransmu the conversion of an atom of one element to an atom of tation another element transuranium the elements in the periodic table with atomic numbers elementstransuranium above 92 elements fissionfission the splitting of a nucleus into smaller fragments neutron a method to slow down neutrons so that they can be moderationneutron captured by the reactor fuel to continue the chain reactio moderation neutron decreases the number of slow neutrons absorbtionneutron absorbtion fusionfusion two nuclei combining to produce a nucleus of heavier mass ionizing radiation that knocks electrons off some atoms of the radiationionizing bombarded substance to produce ions radiation geiger a gas-filled metal tube to detect radiation countergeiger counter scintillation a phosphor used to detect radiation counterscintillation counter film badgefilm several layers of photo graphic film covered with black badge lighproof paper encased in a plastic or metal holder
Table 11:
acidic solutions, 10
activated complex, 9
activation energy, 9
addition reaction, 7
alcohol, 7
aldehydes, 8
aliphatic compounds, 7
alkaline solutions, 10
alkanes, 6
alkenes, 6
alkyl group, 6
alkyl halides, 7
alkynes, 6
alpha particles, 12
alpha radiation, 12
amino acid, 8
anion, 1
antibonding orbital, 3
aqueous solutions, 4
arenes, 7
aromatic compound, 7
aryl halides, 7
asymmetric carbon, 7
band of stablity, 12
basic solutions, 10
Benedict's test, 8
bent triatomic, 4
beta raditation, 12
boiling point elevation, 5
bond
coordinate covalent, 2
covalent, 3
dissociation energy, 3
double covalent, 2
hydrogen, 3
ionic, 1, 2
metallic, 1, 2
nonpolar covalent, 3
pi, 3
polar, 3
polar covalent, 3
sigma, 3
single covalent, 2
triple covalent, 2
bonding orbital, 2
branced chain alkane, 6
Brownian motion, 5
buffer capacity, 11
buffers, 11
carbohydrate, 8
carbonyl group, 7
carboxyl group, 8
carboxylic actids, 8
cation, 1
Châtelier's principle, 9
chemical equilibrium, 9
cis configuration, 6
colligative properties, 5
colloids, 5
common ion, 11
common ion effect, 11
concentrated solution, 5
concentration, 5
condensed structural formula, 6
continuous chain alkanes, 6
coordination number, 1
cracking, 7
cyclic hydrocarbons, 7
dehydrogenation reaction, 8
deliquescent, 4
denatured alcohol, 7
desiccants, 4
Diamagnetic, 4
dilute solution, 5
dipole, 3
dipole interactions, 3
disaccharides, 8
dispersion forces, 3
ductile, 2
effloresce, 4
electrolyte
strong, 5
weak, 5
electrolytes, 4
Electron dot structures, 1
elementary reaction, 9
emulsions, 5
endergonic, 9
entropy, 9
equilibrium constant, 9
equilibrium position, 9
equivalence point, 11
equivalent, 11
esters, 8
esthers, 8
exergonic, 9
fatty acids, 8
Fehling's test, 8
fermentation, 7
film badge, 13
first-order reaction, 9
fission, 12
free energy, 9
freezing point depression, 5
functional group, 7
fusion, 13
gamma radiation, 12
geiger counter, 13
geometric isomers, 7
Gibbs free energy, change in, 9
gram equivalent, 11
half-life, 12
half-reaction, 12
half-reaction method, 12
halied ions, 1
halocarbons, 7
Henry's Law, 5
heterogeneous reactions, 9
homologous series, 6
Hybrid States, 4
hybridization, 3
hybridized electron state, 3
hydration reaction, 7
hydrocarbons, 6
hydrogenation reaction, 7
hydronium ion, 10
hydroxide ion, 10
hydroxyl group, 7
hygroscopic, 4
immiscible, 5
inhibitor, 9
intermediate, 9
ionizing radiation, 13
ion-product constant for water, 10
isoelectronic, 1, 2
IUPAC System, 6
ketones, 8
kinetic theory, 10
law of disorder, 9
linear triatomic, 4
lipid, 8
malleable, 2
miscible, 5
molal boiling point elevation constant, 6
molal freezing point depression constant, 6
molality, 6
molarity, 5
mole fraction, 6
molecular orbital, 2
monomers, 8
monosaccharides, 8
network solids, 3
neutral solution, 10
neutron absorbtion, 12
neutron moderation, 12
nonelectrolytes, 5
non-spontaneous reactions, 9
normality, 11
octet rule, 1
oxidation, 12
oxidation number, 12
oxidation number change method, 12
oxidation--reduction reactions, 11
oxidizing agent, 12
paramagnetic, 2, 4
peptide, 8
peptide bond, 8
polar molecule, 3
polymer, 8
polypeptide, 8
polysaccharides, 8
positron, 12
protein, 8
radiation, 12
radioactive decay, 12
radioactivity, 12
radioisotopes, 12
rate law, 9
reaction mechanism, 9
reaction rate, 9
redox reactions, 12
reducing agent, 12
reduction, 12
resonance, 2
reversible reaction, 9
salt hydrolysis, 11
saponification, 8
saturated solution, 5
scintillation counter, 13
self-ionization, 10
solubility, 5
solutbility product constant, 11
solute, 4
solvation, 4
Rate of, 6
solvent, 4
specific rate constant, 9
spontaneous reaction, 9
standard of entropy, 9
stereoisomers, 7
structural isomers, 6
structure formula, 2
substituent, 6
substitution, 7
supersaturated solution, 5
surface tension, 4
surfactants, 4
suspensions, 5
tetrahedral, 4
tetrahedral angle, 3
trans configuration, 6
transition state, 9
transmutation, 12
transuranium elements, 12
Triagonal bipyramidal, 4
triglycerides, 8
trigonal planar, 4
Tyndall effect, 5
unsaturated, 5
unsaturated compounds, 6
unshared pairs, 2
Valence Electrons, 1
van der Waals forces, 3
VSEPR theory, 3
water of hydration, 4
waxes, 8
zwitterions, 8